
Stoma Edu J. 2024;11(1-2):
pISSN 2360-2406; eISSN 2502-0285
www.stomaeduj.com
Original Articles
35-41
Fidelity and dimensional stability are two essential
physical characteristics characterizing the perfor-
mance of synthetic elastomers as impression
materials [17,18,19] as a result of remarkable advances
in synthetic polymer chemistry. These characteristics
express the ability of silicone and polyetheric
impression materials to reproduce the surface
details of dental preparations in a very precise way
and to maintain these details over a period of time
sucient to allow precise patterns to be cast under
optimal conditions. Factors aecting the delity
and dimensional stability of elastomeric impression
materials [20,21] include changes that occur during
polymerization, such as volumetric reductions, loss
of alcoholic groups, which cause contractions and,
last but not least, temperature, disinfectants and
impressioning techniques. Synthetic elastomers
(polysuldes, polysiloxane polyethers), according
to international norms (ISO) are classied as follows:
type I - putty (Putty); type II - with increased viscosity
for preliminary impressions (Heavy bodied); type III
- medium viscosity for a wide range of impressions
(Regular); type IV- low viscosity (uids) for syringe
injection techniques (Light bodied).
Silicone elastomers (silicones) are compounds
containing organic groups, one or more of which
are covalently bonded to a silicon atom [22,23,24].
Silicones are sold in three viscosity variants (high,
medium and low), each in a two-component system
(base and catalyst). The base is packaged in tubes
(silicones of medium and uid consistency) or in
cartons (those with chitous consistency), and the
catalyst (activator) in vials, when in liquid form,
or in tubes when presented as a paste. Silicone
elastomers used for impressioning are obtained
either by polycondensation reactions or by polyaddi-
tion reactions [25,26]. The addition silicones are
composed of base paste (polyvinylsiloxane) and
accelerator paste (polyxyloxane with terminal vinyl
group, organometallic catalyst – chloroplatinic acid).
Condensation silicones are composed of base paste
(polydimethylsiloxane, inert inorganic mass that
ensures the necessary viscosity and rigidity consists
of pyrolytic silica and titanium dioxide (plasticizer))
and accelerator paste (tin octotate, ethyl orthosilicate,
sometimes chromium oxide or palladium metal
particles with the role of capturing hydrogen that is not
benecial to the footprint surface). Siloxane polyvinyl
materials are an improvement in condensation
silicones. Both are based on polydimethyl siloxane
polymer, but their plug processes are distinct due
to the presence of dierent terminal groups. In
the basic substance, a polymer containing silane
terminal groups called polymethyl hydrogen siloxane
copolymer is present, which has a low molecular
weight. Vinyl polydimethyl siloxane is present in the
accelerator substance, although it comprises vinyl
terminal groups, and this polymer has a moderately
low molecular weight. As a homogeneous metallic
complex catalyst, chloroplatinic acid is also a
component of the accelerator material. When silane
and vinyl groups are combined, an addition process
takes place. The properties of siloxane polyvinyl vary
greatly in terms of viscosity, working and grip time,
breaking energy, elastic recovery and deformation,
dimensional stability, creep conformity, radiopacity,
etc. [27]. It is common when uid silicone, with low
viscosity, is used in the second time in impressioning
techniques, after using chitous material. Each material
has its own advantages and disadvantages, and its
choice is made based on factors such as accuracy,
ease of use and patient comfort [28]. They must
demonstrate excellent detail reproduction, good
tear resistance, be biocompatible and non-toxic, etc.
The evaluation of basic characteristics such as delity
and dimensional stability, but also the comparative
analysis of the results obtained when evaluating
them by the three study methods, demonstrates the
possibility of successful use of elastomeric addition
and condensation materials [30, 37, 38, 39].
2. MATERIALS AND METHODS
The material used in the experiments is polyvinyl
siloxane of dierent uidities. For each high and
medium uidity, two samples were obtained, one
condensation and the other addition.
2.1. Preparation of test samples
a) The medium uidity condensation polyvinyl
siloxane sample is prepared from Zhermack Zetaplus
chitous silicone and Zhermack catalyst, indurent
(induced) gel. The two components were thoroughly
mixed to remove air bubbles (mixing time about 30
seconds) until a homogeneous, grey mixture was
obtained (Fig. 1a).
b) The medium uidity addition polyvinyl siloxane
sample was prepared from Zhermack elite HD+
chitous silicone and a Zhermack elite HD+ catalyst by
manually mixing the two components to eliminate
air bubbles for about 30 seconds. A homogeneous
yellow-orange material was obtained (Fig. 1b).
c) The high uidity condensation polyvinyl siloxane
sample was prepared from Lascod silicone Silaxyl
Light body = uid consciousness, together with a
universal catalyst, Coltene Speedex activator. Mixing
these two materials was done on waxed paper, by
mixing vigorously with a spatula and pressing on
waxed paper to remove air bubbles. The mixing time
is approximately 30 seconds until a homogeneous
blue material is obtained (Fig. 2a).
d) The high-uidity addition polyvinyl siloxane
sample was prepared from a Zhermack elite HD+
super light body consistency. A pink sample of
suitable consistency (neither hard nor soft) was
obtained (Fig. 2b).
Vasilescu VG et al.
Figure 1a. Siloxane polyvinyl samples: a. condensation with medium fluidity.
Figure 1b. Siloxane polyvinyl samples: b. addition with medium fluidity.
Figure 2a. Siloxane polyvinyl samples: a. High fluidity condensation.
Figure 2b. Siloxane polyvinyl samples: b. high fluidity addition.
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